Vincenzo Passarelli

 

 

Profesor de Química

Centro Universitario de la Defensa
Academia General Militar
Ctra. Huesca s/n
50090 Zaragoza
Tel. +34 976 739863

Formación

Licenciado en Química, Universidad de Pisa-Italia, 1998
Doctor en Química, Scuola Normale Superiore, Pisa-Italia, 2002

Estancias Posdoctorales

ICIS-CNR, Padova, Italia, 2002-2003
Departamento de Química, Universidad de Pisa, Italia, 2004-2005
Departamento de Química Inorgánica, Universitat de Valencia, 2005-2006
ICMA-CSIC, Universidad de Zaragoza, 2006-2009
Departamento de Química Inorgánica, Universidad de Almería, 2009-2010

Proyectos de investigación vigentes

Arquitecturas metal-ligando con aplicación al diseño de catalizadores homogéneos e híbridos (ref. CTQ2016-75884-P)
Catalizadores metálicos enantioselectivos basados en ligandos tetradentados (ref. UZCUD2016-CIE-05)
Diseño y evaluación de catalizadores en procesos químicos sostenibles (ref. CTQ2013-42532-P).

Artículos en revistas

  1. Experimental and Theoretical Mechanistic Investigation on the Catalytic CO2 Hydrogenation to Formate by a Carboxylate-Functionalized Bis(N‑heterocyclic carbene) Zwitterionic Iridium(I) Compound, Raquel Puerta-Oteo, Markus Hölscher, M. Victoria Jimenez, Walter Leitner, Vincenzo Passarelli, Jesus J. Perez-Torrente, Organometallics, 2017, DOI: 10.1021/acs.organomet.7b00509.
  2. The Stepwise Reaction of Rhodium and Iridium Complexes of formula [MCl2(κ4C,N,N’,PL)] with Silver Cations: A Case of trans-Influence and Chiral Self-Recognition, María Carmona, Leyre Tejedor, Ricardo Rodríguez, Vincenzo Passarelli, Fernando J. Lahoz, Pilar García-Orduña and Daniel Carmona, Chem. Eur. J., 2017, 10.1002/chem.201702711
  3. Reversible Small Molecule Interactions with Coordinatively Unsaturated Metal Centres Held in Metallathiaborane Clusters,
    Jonathan Bould, Vincenzo Passarelli, Luis A. Oro, Ramón Macias, Eur. J. Inorg. Chem., 2017, 10.1002/ejic.201700539
  4. Stereospecific control of the metal-centred chirality of rhodium(III) and iridium(III) complexes bearing tetradentate CNN’P ligands, María Carmona, Ricardo Rodríguez, Isabel Méndez, Vincenzo Passarelli, Fernando J. Lahoz, Pilar García-Orduña and Daniel Carmona, Dalton Trans., 2017, 46, 7332–7350, DOI: 10.1039/C7DT01446E.
  5. A Well-Defined NHC-Ir(III) Catalyst for the Silylation of Aromatic C–H Bonds: Substrate Survey and Mechanistic Insights, Laura Rubio Perez, Manuel Iglesias, Julen Munarriz, Victor Polo, Vincenzo Passarelli, Jesús J. J. Pérez-Torrente and Luis A Oro, Chem. Sci., 2017,8, 4811-4822 DOI: 10.1039/C6SC04899D.
  6. Divergent Reactivity of 2-Vinylpyridine and 1-Vinylpyrazole in Rhodium-Phosphine Systems: C-H Activation and Dinuclear Chemistry, Ramón Azpíroz, Vincenzo Passarelli, Ricardo Castarlenas, Jesús J. Pérez-Torrente, and Luis A. Oro, J. Mex. Chem. Soc. 2017, 61(2), 138-145. Special issue in memory of Prof. Dr. Roberto Sanchez Delgado.
  7. Synthesis and catalytic activity of new, water-soluble mono- and dinuclear ruthenium(II) complexes containing 1,3,5-triaza-7-phosphaadamantane: Study of the effect of the visible light, Antal Udvardy, Manuel Serrano-Ruiz, Vincenzo Passarelli, Evelin Bolyog-Nagy, Ferenc Joó, Ágnes Kathó, Antonio Romerosa, Inorg. Chim. Acta, 2017, http://dx.doi.org/10.1016/j.ica.2017.04.054.
  8. Temperature Dual Enantioselective Control in a Rhodium-Catalyzed Michael-Type Friedel-Crafts Reaction: A Mechanistic Explanation, Isabel Méndez, Ricardo Rodríguez, Víctor Polo, Vincenzo Passarelli, Fernando J. Lahoz, Pilar García-Orduña, and Daniel Carmona, Chem. Eur. J., 2016, 22, 11064-11083
  9. Postsynthetic Modifications of [2,2,2-(H)(PPh3)2-closo-2,1-RhSB8H8] with Lewis Bases: Cluster Modular Tuning, Susana Luaces, Vincenzo Passarelli, María José Artigas, Fernando J. Lahoz, Luis A. Oro, Ramon Macias, Dalton Trans., 2016, 45, 8622-8636.
  10. En route to phosphonato iridium(I) complexes: the decisive effect of an intramolecular hydrogen bond, Vincenzo Passarelli, Jesús J. Pérez-Torrente, Luis A. Oro, Dalton Trans., 2016, 45, 951-962.
  11. Intramolecular C–H oxidative addition to iridium(I) triggered by trimethyl phosphite in N,N’–diphophanesilanediamine complexes, Vincenzo Passarelli, Jesús J. Pérez-Torrente, Luis A. Oro, Dalton Trans., 2015, 44, 18596-18606.
  12. Rhodium(I)-N-Heterocyclic Carbene Catalyst for Selective Coupling of N-Vinylpyrazoles with Alkynes via C–H Activation, Ramón Azpíroz, Laura Rubio-Pérez, Andrea Di Giuseppe, Vincenzo Passarelli, Fernando J. Lahoz, Ricardo Castarlenas, Jesús J. Pérez-Torrente, and Luis A. Oro, ACS Catal., 2014, 4, 4244-4253.
  13. Intramolecular C−H Oxidative Addition to Iridium(I) in Complexes Containing a N,N′‑Diphosphanosilanediamine Ligand, Vincenzo Passarelli, Jesús J. Pérez-Torrente, Luis A. Oro, Inorg. Chem., 2014, 53, 972−980
  14. Reactivity of Novel N,N’-Diphosphino-Silanediamine-Based Rhodium(I) Derivatives, Vincenzo Passarelli and Franco Benetollo, Inorg. Chem., 2011, 50, 9958–9967.
  15. Synthesis, spectroscopy and electrochemistry of new 4-(4-acetyl-5-substituted-4, 5-dihydro-1, 3,4-oxodiazol-2-yl)methoxy)-2H-chromen-2-ones as a novel class of potential antibacterial and antioxidant derivatives, N. Hmadi, V. Passarelli, A. Romerosa, C. R. Chimie, 2011, 14, 548-555.
  16. Comparative study of [RuClCp(HdmoPTA-kP)(PPh3)][CF3SO3] and the heterobimetallic complexes [RuClCp(PPh3)-m-dmoPTA-1kP:2k2N,N’-M(acac-k2O,O’)2] (M= Co, Ni, Zn; dmoPTA = 3,7-dimethyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane), Adrián Mena-Cruz, Pablo Lorenzo-Luis, Vincenzo Passarelli, Antonio Romerosa and Manuel Serrano-Ruiz, Dalton Trans., 2011, 40, 3237-3244.
  17. Rhodium(III)-Catalyzed Dimerization of Aldehydes to Esters, Cristina Tejel, Miguel A. Ciriano and Vincenzo Passarelli, Chem. Eur. J., 2011, 17, 91-95
  18. Synthesis and reactivity of the novel hydride derivative RhHCl(TIMP3) (HTIMP3 = tris[1-(diphenylphosphino)-3-methyl-1H-indol-2-yl]methane), Marco Ciclosi, Francisco Estevan, Pascual Lahuerta, Vincenzo Passarelli, Julia Pérez-Prieto and Mercedes Sanaú, Dalton Trans., 2009, 2290–2297
  19. Synthesis, variable temperature NMR investigations and solid state characterization of novel octafluorofluorene compounds, Fabio Marchetti, Fabio Marchetti, Francesco Masi, Guido Pampaloni, Vincenzo Passarelli, Anna Sommazzi, Silvia Spera, Journal of Fluorine Chemistry 130 (2009) 341–347
  20. Formation of a bridging imido d6 rhodium compound by nitrene capture. Insertion and Cycloaddition Reactions, Cristina Tejel, Miguel Ángel Ciriano, Sonia Jiménez, Vincenzo Passarelli, José Antonio Lopez, Inorg. Chem., 2008, 47, 10220-10222
  21. Intervalent Bis(m-aziridinato)MII—MI Complexes (M=Rh, Ir): Delocalized Metallo-Radicals or Delocalized Aminyl Radicals?, Cristina Tejel, Miguel Ángel Ciriano, Vincenzo Passarelli, José Antonio Lopez, Chem. Eur. J., 2008, 14, 10985-10998
  22. Stabilization of the hydroperoxo ligand: k1-O,k2-O’ dimetallic coordination mode, Cristina Tejel, Miguel Ángel Ciriano, Sonia Jiménez, Vincenzo Passarelli, José Antonio Lopez, Angew. Chem., Int. Ed., 2008, 47, 2093-2096
  23. Unprecedented Iridium(III) Catalyst for Stereoselective Dimerization of Phenylacetylene, Marco Ciclosi, Francisco Estevan, Pascual Lahuerta, Vincenzo Passarelli, Julia Pérez-Prieto, Mercedes Sanaú, Adv. Synth. Catal., 2008, 350, 234-236
  24. Unprecedented reversible coupling of alkynyl and phosphide ligands on a dinuclear platinum framework, Alberto Albinati, Valeria Filippi, Piero Leoni, Lorella Marchetti, Marco Pasquali, Vincenzo Passarelli, Chem. Commun., 2005, 2155-2157
  25. Perfluorofluorenyl anions and their use as co-catalysts in the zirconocene-promoted polymerization of olefins, Fausto Calderazzo, Francesco Masi, Guido Pampaloni, Vincenzo Passarelli,Roberto Santi, Anna Sommazzi, Silvia Spera, Francesca Tumminia, Journal of Organometallic Chemistry 690 (2005) 4886–4898
  26. Structure and protonation of the bis-ethylene adduct [Pt(m-PBut2)(m2-CH2=CH2)]2. Pt–H–P agostic interaction and proton scrambling, Piero Leoni, Fabio Marchetti, Lorella Marchetti, Vincenzo Passarelli, Chem. Commun., 2004, 2346-2347
  27. Unsymmetrically Substituted Dimethyldiaminosilanes as Ligands towards Zirconium(IV), Vincenzo Passarelli, Pierino Zanella, Eur. J. Inorg. Chem., 2004, 4439-4446
  28. The Ligating Ability of Functionalised Diaminodimethylsilanes towards Zirconium(IV), Vincenzo Passarelli, Franco Benetollo, Pierio Zanella, Eur. J. Inorg. Chem., 2004, 1714-1723
  29. Solution dynamics and molecular structure elucidation of novel aluminium derivatives containing diaminodimethylsilane ligands, Vincenzo Passarelli, Franco Benetollo, Pierino Zanella, Dalton Trans., 2004, 1424-1431
  30. Synthesis and characterisation of novel zirconium (IV) derivatives containing the bis-amido ligand SiMe2(NRR’)2, Vincenzo Passarelli, Franco Benetollo, Pierino Zanella, Giovanni Carta, Gilberto Rossetto, Dalton Trans., 2003, 1411-1418
  31. Synthesis and structural characterization of iron(II) derivatives of heterocyclic tridentate amines, Fausto Calderazzo, Ulli Englert, Chunhua Hu, Fabio Marchetti, Guido Pampaloni, Vincenzo Passarelli, Annamaria Romano, Roberto Santi, Inorganica Chimica Acta 344 (2003) 197-206
  32. Synthesis, reactivity and structures of mono- and dihaloacetato complexes of copper(I) and copper(II), Fausto Calderazzo, Nausica Donati, Ulli Englert, Fabio Marchetti, Guido Pampaloni, Vincenzo Passarelli, Inorganica Chimica Acta 346 (2003) 100-110
  33. Synthesis of amino and amido aluminium derivatives and investigation of their dynamics in solution, Vincenzo Passarelli, Giovanni Carta, Gilberto Rossetto, Pierino Zanella, Dalton Trans., 2003, 1284-1291
  34. Aminolysis of the Si–Cl bondand ligand exchange reaction between silicon amido derivatives and SiCl4: synthetic applications and kinetic investigations, Vincenzo Passarelli, Giovanni Carta, Gilberto Rossetto, Pierino Zanella, Dalton Trans., 2003, 413-419
  35. 1,10-Phenanthroline-5,6-dione as a building block for the synthesis of homo- and heterometallic complexes, Fausto Calderazzo, Guido Pampaloni, Vincenzo Passarelli, Inorganica Chimica Acta 330 (2002) 136–142
  36. Synthesis and characterisation of mono- and bimetallic derivatives of Groups 4 and 5 with 2,5-dimethoxy-1,4-benzoquinone, Fausto Calderazzo, Ulli Englert, Guido Pampaloni, Vincenzo Passarelli, J. Chem. Soc., Dalton Trans., 2001, 2891-2898
  37. Synthesis, characterization and reactivity of manganese (II) and iron (II) trifluoroacetates. Crystal and molecular structure of two linkage isomers of polynuclear [Mn(CF3COO)2(THF)2]n, Fausto Calderazzo, Ulli Englert, Guido Pampaloni, Vincenzo Passarelli, Giovanna Serni, Ruimin Wang, Can. J. Chem., 2001, 79, 495-501
  38. Synproportion reactions between copper(II) trihalogeno-acetates Cu(CX3COO)2, X = F, Cl or Br, and copper in the presence of carbon monoxide, Daniela Belli Dell’Amico, Rocco Alessio, Fausto Calderazzo, Fabrizio Della Pina, Ulli Englert, Guido Pampaloni, Vincenzo Passarelli, J. Chem. Soc., Dalton Trans., 2000, 2067-2075
  39. Coordination properties of 1,10-phenanthroline-5,6-dione towards Groups 4 and 5 metals in low and high oxidation states, Fausto Calderazzo, Fabio Marchetti, Guido Pampaloni, Vincenzo Passarelli, J. Chem. Soc., Dalton Trans., 1999, 4389-4396

Cápitulos de libros

Bond Activation and Catalysis, In Comprehensive Inorganic Chemistry II (Second Edition), F.J. FERNÁNDEZ-ALVAREZ, M. IGLESIAS, L.A. ORO and V. PASSARELLI, edited by Jan Reedijk and Kenneth Poeppelmeier, Elsevier, Amsterdam, 2013, Pages 399-432, ISBN 9780080965291 (Capítulo de libro).

Patentes

Activating organometallic composition for (co)polymerization of alpha-olefins comprising fluorinated cyclopentadienyl compounds. Anna Sommazzi, Francesco Masi, Giampietro Borsotti, Roberto Santi, Fausto Calderazzo, Guido Pampaloni, Vincenzo Passarelli, US 2004/0198934 A1, PCT/EP02/07684, fecha de prioridad: 20 de Julio de 2001 (M12001A001554, Italia), entidad titular: Polimeri Europa SPA, Via E. Fermi 4, I-72100 Brindisi, Italia

PRÓXIMOS EVENTOS

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21 SEP
 
 

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